| 1 |
JEWELRY |
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| 2 |
Silver
Soldering |
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Cadmium
extremely toxic; Antimony highly toxic; flux fumes highly toxic |
Silver
particles cause blue-black stain |
Carcinogenic; thermal burns; infrared radiation; flammable; acids
corrosive |
Don't use
cadmium, avoid antimony; use borax fluxes, instead of fluoride; wear
respirator, gloves, goggles w/#4 shade; use ventilation; use Sparex; don't
use asbestos; if acid splashes, rinse off |
| 3 |
Soldering |
Lead highly
toxic, Antimony highly toxic |
Lead highly
toxic; Antimony highly toxic; flux fumes moderately irritating |
Zinc
chloride corrosive; flux fumes irritating to eyes |
Hot metal
can cause thermal burns |
Use lead-
and antimony-free solders; avoid zinc chloride and rosin fluxes; use
respirator, ventilation; avoid contact w/hot soldering iron |
| 4 |
Lost Wax
Casting |
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Silica
highly toxic; cuttlebone dust irritating |
Sodium
silicate moderately toxic |
Molten metal
can splash and burn |
Use
nonsilica plaster; do mixing of silica in glove box; wear respirator,
gloves, goggles; wet mop dust; clean cuttlebone; wet sand; make sure
centrifugal casting equipment is balanced, w/protective
shield |
| 5 |
Electroplating |
Cyanide
salts extremely toxic |
Cyanide
salts highly toxic |
Cyanide
salts highly toxic; gold salts can cause allergic reactions |
Acid added
to cyanide forms hydrogen cyanide (extremely toxic); risk of
shock |
Avoid
cyanide plating solution; send piece out to be plated; use cyanide
solution in laboratory hood only; keep antidote kit available; if
poisoning occurs, give amyl nitrite; don't touch wires; don't pour cyanide
in sink |
| 6 |
Annealing,
Cleaning, Polishing,& Finishing |
Cyanide
extremely toxic |
Cyanide
extremely toxic |
Cyanide
extremely toxic |
Sodium &
Potassium cyanide extremely toxic |
Avoid
cyanide plating solution; use cyanide solution in lab hood only; keep
antidote kit available; if poisoning occurs, give amyl nitrite; don't pour
cyanide down sink |
| 7 |
ENAMELING |
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| 8 |
Cleaning the
Metal Surface |
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Kiln/torch
fumes haz.; nitrogen dioxide gas highly toxic |
Sulfuric,
nitric acids highly corrosive; diluted acids, Sparex irritating |
Kilns/torches can cause thermal burns |
Wear
welder's gloves, long-sleeve cotton shirts, splash goggles, protect.
apron; use tongs; kiln should have canopy hood; avoid fire; if acid
spills, rinse w/water; use ventilation; neutralize acid w/baking
soda |
| 9 |
Preparing
Enamels |
Lead highly
toxic |
Lead highly
toxic |
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Lead-safe
doesn't mean it doesn't contain lead |
Use
lead-free, ready-made enamels; place sifters on top of each other to
minimize dust; sift in glove box; wear respirator, gloves; don't eat,
smoke, drink in studio; wash hands after working |
| 10 |
Applying
Enamels |
Turpentine
moderately toxic |
Gum
tragacanth irritating, enamel dust highly toxic; turpenine moderately
toxic |
Enamel dust
irritating; turpentine moderately toxic; potash corrosive |
Contact
w/ferric chloride or nitric acid haz. to skin & eyes |
Brush/dip
enamels instead of dusting/spraying; spray in spray booth; use respirator;
wear gloves; avoid accidental ingestion; prevent fire; use ferric chloride
instead of nitric acid; don't heat ferric chloride |
| 11 |
Firing
Enamels |
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Metals,
fluorides emitted are haz. |
Hot kilns
emit infrared radiation, causing cataracts |
Hot enamel
can cause thermal burns |
All
enameling kilns should be vented; wear welder's gloves, long-sleeve cotton
shirts; use tongs; use goggles w/shade number of 1.8 to 3 |
| 12 |
Finishing
Enamels |
Hydrofluoric
acid extremely toxic; ammonium bifluoride highly toxic |
Particles
haz.; hydrofluoric acid highly corrosive |
Hydrofluoric
acid highly toxic; ammonium bifluoride highly toxic |
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Do wet
grinding; wear protect. goggles, gloves, face shield; don't use
hydrofluoric acid; use ammonium bifluoride pastes instead; use
hydrofluoric acid in lab hood only; treat hydrofluoric acid as haz.
Waste |
| 13 |
Hazards of
Finished Enamels |
Metals
soluble in stomach acid |
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Enameled
pieces should never be used for holding food or drink because of the risk
of toxic metals leaching into food or liquid |