| 1 |
Acetic Acid,
Glacial |
|
Stop
bath |
Highly
toxic |
Highly
toxic |
Highly
toxic |
Corrosive
and causes severe burns; can be fatal; combustible (Threshold Limit Value
[TLV] 10 ppm |
| 2 |
Alum |
Potassium
aluminum sulfate |
Hardener |
Slightly
toxic to moderately toxic |
Slightly
toxic |
Slightly
toxic |
|
| 3 |
Amidol (see
Diaminophenol hydrochloride) |
|
|
|
|
|
|
| 4 |
Aminophenol |
|
Developer |
Highly
toxic |
Moderately
toxic |
Moderately
toxic |
Prolonged
contact irritating; may cause kidney damage, cyanosis (difficulty
breathing), bronchial asthma |
| 5 |
Ammonium
Alum (See Alum) |
Ammonium
aluminum sulfate |
|
|
|
|
|
| 6 |
Ammonium
Bromide |
|
Bleach
bath |
Moderately
toxic |
Moderately
toxic |
Slightly
toxic |
Inhalation/ingestion causes depression, emaciation, vertigo,
confusion, mental deterioration; vomiting |
| 7 |
Ammonium
Dichromate (See Potassium dichromate) |
|
|
|
|
|
|
| 8 |
Ammonium
Hydroxide |
Ammonia
water |
Intensification, toning, hypo elimination |
Moderately
toxic to highly toxic |
Highly
toxic |
Highly
toxic |
TLV 25 ppm;
can cause burns; mixing w/alkalis forms ammonia gas; mixing w/chlorine
bleach forms poison gas |
| 9 |
Ammonium
Persulfate |
|
Reducing
Solutions |
Moderately
toxic |
Slightly
toxic |
Slightly
toxic |
Strong
oxidizing agent; flammable; emit highly toxic sulfur dioxide
gas |
| 10 |
Ammonium
Thiocyanate (see Potassium thiocyanate) |
|
|
|
|
|
|
| 11 |
Ammonium
Thiosulfate (see Sodium thiosulfate) |
|
|
|
|
|
|
| 12 |
p-Benzoquinone |
Para-benzoquinone, quinone |
Holography
bleach |
Highly
toxic |
Highly
toxic |
Highly
toxic |
TLV 0.1 ppm;
Causes severe skin/eye irritation; high exposure causes pneumonia;
overexposure can cause brain damage; combustible solid |
| 13 |
Bleach,
household |
5% sodium
hypochlorite solution |
Hypo
eliminator |
Moderately
toxic |
Moderately
toxic |
Moderately
toxic |
Repeated
exposure can cause dermatitis; heating releases highly toxic chlorine gas;
addition of ammonia forms highly poisonous gas |
| 14 |
Borax |
Sodium
tetraborate, sodium metaborate, sodium pyroborate |
Developing
bath |
Moderately
toxic |
Moderately
toxic |
Slightly
toxic |
TLV 1-5
mg/m3; alkaline powder; absorption causes nausea, abdominal pain,
diarrhea, vomiting, skin rash |
| 15 |
Boric
acid |
|
Buffer |
Moderately
toxic to highly toxic |
Moderately
toxic |
Slightly
toxic |
Acidic
powder; absorption causes nausea, abdominal pain, diarrhea, vomiting, skin
rash |
| 16 |
Bromine |
|
Holography
bleach |
Highly
toxic |
Highly
toxic |
Highly
toxic |
TLV 0.1 ppm;
corrosive; can cause severe burns; absorbed through skin; oxidizing agent;
poisonous gases produced in fires |
| 17 |
Catechin |
Catechol,
pyrocatechol, o-dihydroxybenzene |
Developer |
Highly
toxic |
Highly
toxic |
Highly
toxic |
TLV 5 ppm
(skin); absorbed through skin; inhalation causes cyanosis, anemia,
convulsions, vomiting, liver & kidney damage; DON'T USE |
| 18 |
Chlorquinol |
Chlorhydroquinone |
Developer |
Highly
toxic |
Moderately
toxic |
Moderately
toxic |
Inhalation
causes cyanosis, anemia, convulsions, vomiting, liver & kidney damage;
DON'T USE |
| 19 |
Chrome Alum
(see Potassium chrome alum) |
|
|
|
|
|
|
| 20 |
Diaminophenol Hydrochloride |
Hydroxy-p-phenylenediamine hydrochloride |
Developer |
Highly
toxic |
Highly
toxic |
Moderately
toxic |
May be
absorbed through skin; skin contact causes severe irritation; causes
bronchial asthma, gastritis, vertigo, tremors, coma; DON'T
USE |
| 21 |
Diethanolamine |
|
Color
developing baths |
Moderately
toxic |
Moderately
toxic |
Moderately
toxic |
TLV 3 ppm;
alkaline; irritating to eyes/respiratory system; may cause mild liver
damage |
| 22 |
Diethyl-p-Phenylene Diamine (see p-phenylene diamine) |
|
|
|
|
|
|
| 23 |
Dimethyl-p-Phenylene Diamine (see p-phenylene diamine) |
|
|
|
|
|
|
| 24 |
Disodium
Phosphate |
|
Color bleach
bath |
Moderately
toxic |
Slightly
toxic |
Slightly
toxic |
May cause
irritation to skin and eyes |
| 25 |
Ethoxydiglycol |
Diethylene
glycol ethyl ether, 2-(2- ethoxyethyl) ethanol, carbitol |
Color
processing solvent |
Moderately
toxic |
Slightly
toxic |
Slightly
toxic |
Probable
human development toxicant; causes irritation; absorbed through skin;
similar to ethylene glycol; not volatile unless heated |
| 26 |
Ethylene
Diamine |
|
Color
developing baths |
Moderately
toxic |
Highly
toxic |
Highly
toxic |
TLV 10 ppm;
corrosive to skin and eyes; may be absorbed through skin; liver and kidney
damage, asthma can occur |
| 27 |
Ethylenediamine- tetraacetic Acid (EDTA) and Salts |
|
Color
developing baths, holography |
Moderately
toxic |
Slightly
toxic |
Slightly
toxic |
EDTA and its
salts chelate metal ions, including calcium; sodium salts cause muscular
spasms |
| 28 |
Ethylene
Glycol |
Glycol,
1,2-ethanediol |
Color
developing baths |
Moderately
toxic |
Slightly
toxic |
Moderately
toxic |
TLV-C 50
ppm; Ingestion is most serious problem; 3 ounces can be fatal in adults;
affects kidneys, liver, central nervous system; low
volatility |
| 29 |
Farmer's
Reducer (see Potassium ferricyanide) |
|
|
|
|
|
|
| 30 |
Ferric alum
(see alum) |
Ferric
ammonium sulfate |
Toning
solution |
|
|
|
|
| 31 |
Ferric
Ammonium Citrate |
|
Cyanotype |
Moderately
toxic |
Slightly
toxic |
Slightly
toxic |
TLV 1 mg/m3;
Soluble iron salts slightly irritating; can cause poisoning if ingested in
large amounts (especially by children) |
| 32 |
Ferric
Oxalate (see Potassium oxalate) |
|
|
|
|
|
|
| 33 |
Formaldehyde |
Formalin |
Hardener,
stabilizer |
Moderately
toxic to highly toxic |
Highly
toxic |
Moderately
toxic |
TLV-C 0.3
ppm; probable carcinogen, mutagen; irritant; poisonous by ingestion; may
cause asthma, allergic reactions |
| 34 |
Freon 11 and
12 |
Dichlorofluorometh-ane, trichlorofluoro-methane |
Film
cleaner |
Slightly
toxic |
Slightly
toxic |
Slightly
toxic |
TLV 1000
ppm; may cause respiratory irritation, narcosis, irregular heart rhythms;
heating produces highly poisonous gases; damages ozone layer |
| 35 |
Glycin |
P-hydroxyphenyl aminoacetic acid |
Developer |
Moderately
toxic |
Moderately
toxic |
Moderately
toxic |
Skin contact
may cause irritation, allergies; inhalation/ingestion may cause anemia,
cyanosis, difficulty breathing, nausea, dizziness |
| 36 |
Gold
Chloride |
|
Toner |
Moderately
toxic |
Moderately
toxic |
Moderately
toxic |
Can cause
severe skin/respiratory allergies; can cause anemia, liver, kidney,
nervous system damage |
| 37 |
Hydrobromic
Acid, Dilute |
|
Holography,
color bleach |
Highly
toxic |
Moderately
toxic |
Moderately
toxic |
TLV 3 ppm;
concentrated acid extremely corrosive; may cause skin, eye irritation;
inhalation may cause lung irritation, possible chronic
bronchitis |
| 38 |
Hydrochloric
Acid |
|
Acid |
Highly
toxic |
Moderately
toxic |
Highly
toxic |
TLV-C 7.5
mg/m3; concentrated acid highly corrosive; may cause skin/eye, lung
irritation; may cause chronic bronchitis |
| 39 |
Hydrogen
Peroxide |
3
1/2% |
Hypo
eliminator |
Slightly
toxic |
Not
significantly toxic |
Slightly
toxic |
Ingestion or
repeated skin contact may cause slight irritation |
| 40 |
Hydroquinone |
|
Developer |
Highly
toxic |
Moderately
toxic |
Moderately
toxic |
TLV 2 mg/m3,
NIOSH C 2 mg/m3; probable mutagen; eye injury may result; may cause
ringing in ears, nausea, dizziness, delirium, coma |
| 41 |
Hydroxylamine Sulfate |
|
Color
neutralizing bath |
Moderately
toxic |
Moderately
toxic |
Moderately
toxic |
Probable
human development toxicant; may cause irritation, allergies, anemia,
cyanosis, convulsions, coma; causes birth defects in rats |
| 42 |
Hypo (see
Sodium thiosulfate) |
|
|
|
|
|
|
| 43 |
Iodine |
|
Reducing
agent |
Highly
toxic |
Highly
toxic |
Moderately
toxic |
TLV-C 0.1
ppm; may cause hypersensitivity reaction & burns; heating produces
highly toxic fumes; ingestion may be fatal because of
corrosivity |
| 44 |
Lead
oxalate |
See also
potassium oxalate |
Platinum
printing |
Highly
toxic |
Highly
toxic |
Moderately
toxic |
PEL 0.05
mg/m3; can cause inorganic lead poisoning; causes weakening, anemia,
headaches, irritability, possible birth defects; corrosive |
| 45 |
Liver of
Sulfur (See Potassium sulfide) |
|
|
|
|
|
|
| 46 |
Mercuric
Chloride |
|
Intensifier,
platinum toner |
Extremely
toxic |
Highly
toxic |
Moderately
toxic |
TLV 0.05
mg/m3 (skin); corrosive; may cause mercury poison.; metallic taste,
salivation, swelling of gums, vomiting, bloody diarrhea; DON'T
USE |
| 47 |
Mercuric
Iodide (see Mercuric Chloride) |
|
|
|
|
|
|
| 48 |
Methyl
Chloroform (see 1,1,1,-trichloro- ethane) |
|
|
|
|
|
|
| 49 |
Metol (see
Monomethyl p-aminophenol sulfate) |
|
|
|
|
|
|
| 50 |
Monoethanolamine |
Ethanolamine, 2-aminoethanol |
Color
developing bath |
Moderately
toxic |
Moderately
toxic |
Slightly
toxic |
TLV 3 ppm;
alkaline; irritating to eyes, respiratory system; may cause lethargy, mild
liver/kidney damage |
| 51 |
Monomethyl
p-Aminophenol Sulfate |
|
Developer |
Moderately
toxic |
Moderately
toxic |
Moderately
toxic |
Skin contact
may cause severe skin irritation, allergies; inhalation/ingestion may
cause anemia, cyanosis, difficulty breathing, dizziness,
nausea |
| 52 |
O-Phenylene
Diamine (See P-phenylene Diamine) |
|
|
|
|
|
|
| 53 |
Oxalic
Acid |
|
Toning
solution, platinum printing |
Highly
toxic |
Highly
toxic |
Highly
toxic |
TLV 1 mg/m3;
causes severe corrosivity, respiratory irritation, allergies, shock,
collapse, possible convulsions, death; may be severe kidney
damage |
| 54 |
Phenidone |
1-phenyl-3-pyrazo-lidone |
Developer |
Moderately
toxic |
Moderately
toxic |
Slightly
toxic |
Least toxic
developer by skin contact; haz. by inhalation or ingestion similar to
those for other developers |
| 55 |
P-Phenylene
Diamine |
Para-phenylenediamine |
Developer |
Highly
toxic |
Highly
toxic |
Moderately
toxic |
TLV 0.1
mg/m3 (skin); may cause severe allergies; may be absorbed through skin;
may cause vertigo, gastritis, liver/spleen damage; AVOID if
possible |
| 56 |
Phosphoric
Acid |
|
Platinum
printing |
Highly
toxic |
Highly
toxic |
Highly
toxic |
TLV 1 mg/m3;
highly corrosive; ingestion can cause severe stomach damage and may be
fatal; may cause irritant dermatitis; diluted acid less haz. |
| 57 |
Platinum
Chloride |
|
Toner,
Platinum printing |
Unknown |
Highly
toxic |
Moderately
toxic |
TLV 0.002
mg/m3; causes severe allergies, asthma; some lung scarring/ emphysema may
occur; people w/red/light hair, most susceptible |
| 58 |
Potassium
Bromide (see Ammonium bromide) |
|
Developing
& intensifying baths |
|
|
|
|
| 59 |
Potassium
Chlorate |
|
Platinum
printing |
Highly
toxic |
Moderately
toxic |
Moderately
toxic |
Strong
oxidizing agent; flammable in contact w/solvents; irritant; causes
gastritis, delayed kidney damage |
| 60 |
Potassium
Chlorochromate |
|
Intensifier |
Moderately
toxic |
Highly
toxic |
Moderately
toxic |
Probable
carcinogen; may cause irritation, ulceration, allergies, eye burns;
gastroenteritis, vertigo, muscle cramps, kidney damage; heating releases
highly toxic chlorine gas |
| 61 |
Potassium
Chloroplatinite (see Platinum chloride) |
|
|
|
|
|
|
| 62 |
Potassium
Chrome Alum |
Chrome Alum,
Chromium potassium sulfate |
Hardener |
Highly
toxic |
Highly
toxic |
Moderately
toxic |
TLV 0.3
mg/m3; possible carcinogen; skin, eye, respiratory irritant |
| 63 |
Potassium
Cyanide |
|
Reducer |
Extremely
toxic |
Highly
toxic |
Highly
toxic |
TLV 5 mg/m3;
may be absorbed through skin; can cause chemical asphyxia; adding acid
forms hydrogen cyanide gas; DON'T USE |
| 64 |
Potassium
Dichromate |
Potassium
bichromate |
Intensifier |
Extremely
toxic |
Extremely
toxic |
Highly
toxic |
TLV 0.05
mg/m3, NIOSH 0.001 mg/m3; probable carcinogen; corrosive; strong oxidizer;
can cause cancer, circulatory collapse, kidney damage; AVOID if
possible |
| 65 |
Potassium
Ferricyanide |
Farmer's
Reducer |
Reducer,
cyanotype |
Moderately
toxic |
Slightly
toxic |
Slightly
toxic |
Heating,
treating w/acid, exposing to uv light can cause release of highly toxic
hydrogen cyanide gas |
| 66 |
Potassium
Iodide |
|
Holography |
Moderately
toxic |
Unknown |
Not
significant |
Known human
teratogen; may cause "iodism", w/symptoms of salivation, sneezing,
inflammation of nasal passages, headache, fever, bronchitis, skin
rashes |
| 67 |
Potassium
Oxalate |
|
Platinum
printing |
Highly
toxic |
Highly
toxic |
Moderately
toxic |
Corrosive to
skin, eyes, nose, throat; ingestion causes intense damage to mouth,
esophagus, stomach, kidney damage; may be fatal by ingestion |
| 68 |
Potassium
Permanganate |
|
Reducer,
hypo eliminator |
Highly
toxic |
Highly
toxic |
Highly
toxic |
Concentrated
solutions & solids are highly corrosive to skin, eyes, mouth, stomach;
dilute solutions are mildly irritating |
| 69 |
Potassium
Persulfate (see Ammonium persulfate) |
|
|
|
|
|
|
| 70 |
Potassium
Sulfide |
Liver of
sulfur |
Toner |
Extremely
toxic |
Moderately
toxic |
Moderately
toxic |
Skin contact
causes skin softening & irritation; dust causes irritation; ingestion
may cause hydrogen sulfide poisoning; mixing w/acid causes highly toxic
hydrogen sulfide gas |
| 71 |
Potassium
Thiocyanate |
|
Color
developing bath |
Highly
toxic |
Slightly
toxic |
Not
significantly toxic |
Ingestion
causes vomiting, delirium, convulsions; poisoning similar to bromide
poisoning; heating/treating w/acid forms extremely toxic hydrogen cyanide
gas |
| 72 |
Pyrogallic
Acid |
Pyrogallol,
1,2,3-trihydroxybenzene |
Developer |
Highly
toxic |
Highly
toxic |
Highly
toxic |
May be
absorbed through skin; inhalation causes severe poisoning w/cyanosis,
anemia, convulsions, vomiting, liver & kidney damage; can be fatal;
DON'T USE |
| 73 |
Selenium
Oxide |
Selenium
dioxide |
Toner |
Highly toxic
to extremely toxic |
Highly
toxic |
Moderately
toxic |
TLV 0.2
mg/m3; may be absorbed through skin; causes irritation; similar to arsenic
poisoning; treatment w/acid forms extremely toxic hydrogen selenide
gas |
| 74 |
Silver
Nitrate |
|
Test for
hypo, Van Dyke process |
Highly
toxic |
Highly
toxic |
Moderately
toxic |
TLV 0.01
mg/m3; corrosive to skin, eyes, mucous membranes; may cause blindness,
gastroenteritis, shock, vertigo, coma, convulsions |
| 75 |
Sodium
Bisulfite |
|
Fixing
bath |
Highly toxic
to extremely toxic |
Highly
toxic |
Moderately
toxic |
TLV 5 mg/m3;
aqueous solution acidic; adding acid forms sulfur dioxide gas |
| 76 |
Sodium
Carbonate (see Sodium hydroxide) |
Soda
ash |
|
|
|
|
|
| 77 |
Sodium
Formaldehyde Bisulfite |
|
Developing
solution |
Moderately
toxic |
Slightly
toxic |
Slightly
toxic |
Not
irritating like formaldehyde; allergies are rare |
| 78 |
Sodium
Hydroxide |
Caustic
soda |
Developing
bath |
Highly
toxic |
Highly
toxic |
Highly
toxic |
TLV-C 2
mg/m3; highly corrosive; ingestion can cause damage to mouth, esophagus,
& can be fatal; inhalation causes chemical pneumonia; dilute alkaline
more corrosive |
| 79 |
Sodium
Nitrate |
|
Color bleach
bath |
Moderately
toxic |
Not
significantly toxic |
Not
significantly toxic |
May be
converted by intestinal bacteria into more toxic nitrites if ingested; can
result in anemia, cyanosis; strong oxidizer |
| 80 |
Sodium
Sulfide (see Potassium Sulfide) |
|
|
|
|
|
|
| 81 |
Sodium
Sulfite |
|
Preservative |
Moderately
toxic |
Moderately
toxic |
Not
significantly toxic |
Causes
irritation; causes colic, diarrhea, circulatory disturbance, central
nervous system depression; heating/ treating w/acid forms highly toxic
sulfur dioxide gas |
| 82 |
Sodium
Thiocyanate (see Potassium thiocyanate) |
|
|
|
|
|
|
| 83 |
Sodium
Thiosulfate |
Hypo |
Fixer |
Slightly
toxic |
Highly
toxic |
Not
significantly toxic |
Ingestion of
large amounts causes purging; old solutions, or those treated w/acid, or
heated, release highly toxic sulfur dioxide gas |
| 84 |
Succinaldehyde |
|
Color
prehardener |
Moderately
toxic |
Moderately
toxic |
Moderately
toxic |
Skin and eye
irritant; not very volatile, so inhalation less of a risk |
| 85 |
Sulfamic
Acid |
|
Color
bleach |
Highly
toxic |
Highly
toxic |
Moderately
toxic |
Corrosive to
skin, eyes, respiratory system, intestinal system; heating/adding acid
forms highly toxic sulfur dioxide gas |
| 86 |
Sulfuric
Acid |
Oleum |
Cleaning |
Highly
toxic |
Highly
toxic |
Highly
toxic |
TLV 1 mg/m3;
concentrate is corrosive to skin, eyes, respiratory system, stomach;
ingestion can be fatal; dilute less haz.; heating releases highly toxic
sulfur oxide gases |
| 87 |
Tertiary-Butylamine Borate |
|
Color
developing bath |
Highly
toxic |
Highly
toxic |
Highly
toxic |
May cause
skin irritation and be absorbed through skin; may cause nervous system
damage |
| 88 |
Thiourea |
Thiocarbamide |
Toning
solution |
Moderately
toxic to highly toxic |
Highly
toxic |
Slightly
toxic |
Probable
carcinogen and mutagen; thiourea causes cancer in rats |
| 89 |
para-Toluenesulfonic Acid |
|
Color
bleaching |
Moderately
toxic |
Moderately
toxic |
Moderately
toxic |
Corrosive;
skin, eye, respiratory irritant; decomposes w/heat or acid to form sulfur
dioxide and hydrogen sulfide |
| 90 |
1,1,1,-Trichloroethane |
Methyl
chloroform |
Film
cleaner |
Moderately
toxic |
Moderately
toxic |
Slightly
toxic |
TLV 350 ppm;
NIOSH 350 ppm; causes irritation, narcosis, heart arrhythmias, death;
chronic exposure may cause liver damage |
| 91 |
Triethanolamine |
|
Color
developing bath, holography |
Slightly
toxic |
Highly
toxic |
Slightly
toxic |
TLV 0.5 ppm;
probable human carcinogen; alkaline; may cause skin reaction; absorbed
through skin; irritating to skin, eyes, respiratory system; may cause mild
liver damage |
| 92 |
Trisodium
Phosphate (see Sodium hydroxide) |
|
Color
developing bath |
|
|
|
|
| 93 |
Uranium
Nitrate |
|
Toner |
Moderately
toxic |
Highly
toxic |
Slightly
toxic |
TLV 0.05
mg/m3; soluble uranium compounds are poorly absorbed, but can cause severe
kidney damage/ failure; DO NOT USE |